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The Collaborative International Dictionary of English v.0.48:

Barb \Barb\, v. t. [imp. & p. p. Barbed (b[aum]rbd); p. pr. & vb. n. Barbing.] 1. To shave or dress the beard of. [Obs.] [1913 Webster] 2. To clip; to mow. [Obs.] --Marston. [1913 Webster] 3. To furnish with barbs, or with that which will hold or hurt like barbs, as an arrow, fishhook, spear, etc. [1913 Webster] But rattling storm of arrows barbed with fire. --Milton. [1913 Webster]