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The Collaborative International Dictionary of English v.0.48:

Purgament \Pur"ga*ment\, n. [L. purgamentum offscourings, washings, expiatory sacrifice. See Purge.] 1. That which is excreted; excretion. [Obs.] [1913 Webster] 2. (Med.) A cathartic; a purgative. [Obs.] --Bacon. [1913 Webster]